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• W2072693503 abstract "The 54-electron cluster cation [Pt3{ReO3}(μ-dppm)3]+, 2, dppm = Ph2PCH2PPh2, reacts with CO, P(OMe)3, Hg, and Tl(acac), acac = MeCOCHCOMe, by addition at the Pt3 center to give the 56-electron cluster cations [Pt3{ReO3}(μ3-L)(μ-dppm)3]+, L = CO (3), Hg (6), or Tl(acac) (5), or [Pt3{ReO3}(L)(μ-dppm)3]+ (4) L = P(OMe)3. Oxidation of 6 in the presence of mercury and NH4[ReO4] gives the bis(mercury) cluster [Pt3(μ3-Hg)2(μ-dppm)3][ReO4]2, 7. The structures of 2[PF6] [cubic, space group Pa3̄, a = 24.495(1) Å, V = 14 697(1) Å3, Z = 8, R = 0.0421 for 3113 reflections with I > 2σ(I)], 6[PF6]·2Me2CO [triclinic, space group P1̄, a = 14.502(5) Å, b = 16.712(7) Å, c = 20.814(6) Å, α = 70.00(3)°, β = 82.52(1)°, γ = 82.39(3)°, V = 4679(3) Å3, Z = 2, R = 0.0688 for 7227 reflections with I > 2σ(I)], and 7[ReO4]2·1.5Me2CO [triclinic, space group P1̄, a = 16.088(5) Å, b = 16.307(7) Å, c = 19.390(7) Å, α = 99.49(2)°, β = 93.70(1)°, γ = 117.30(2)°, V = 4401(4) Å3, Z = 2, R = 0.1010 for 7931 reflections with I > 2σ(I)] have been determined. Cluster 2, which shows exact C3 symmetry, has a nearly tetrahedral Pt3Re core [Pt−Pt = 2.6115(6) Å, Pt−Re = 2.7010(6) Å] while 6 [Pt−Pt = 2.617(2)−2.625(2) Å, Pt−Re = 2.770(2)−2.788(2) Å, Pt−Hg = 2.868(2)−2.976(2) Å] and 7 [Pt−Pt = 2.633(4)−2.646(4) Å, Pt−Hg = 2.754(4)−2.828(4) Å] have approximately trigonal bipyramidal Pt3ReHg and Pt3Hg2 cores, respectively." @default.
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• W2072693503 date "1996-01-01" @default.
• W2072693503 modified "2023-09-26" @default.
• W2072693503 title "Platinum−Rhenium−Mercury and Related Cluster Chemistry" @default.
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• W2072693503 doi "https://doi.org/10.1021/ic950825n" @default.
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