Matches in SemOpenAlex for { <https://semopenalex.org/work/W2072694148> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2072694148 endingPage "134" @default.
- W2072694148 startingPage "119" @default.
- W2072694148 abstract "The aim of this paper is to show how van der Waals forces may account for profound changes in the IR spectra of alkylammonium saturated montmorillonite and the effect of adsorbed water molecules. IR spectra recorded on alkylammonium montmorillonite films submitted to vacuum and after exposure to water vapour show, in addition to the shifts in the stretching and deformation bands expected when hydrogen bonding is present, marked changes in the intensity of the CH 2 and CH 3 deformation bands. All these observations are explained by the following model: (1) in the absence of water, the aliphatic chains are tightly held between the oxygen atoms of the silicate layers with their axis parallel to the 001 planes; and (2) hydration causes a rotation of the organic chain of the dialkyl derivatives while it does not affect the orientation of the monoalkylammonium cations. Moreover in the former situation, the symmetric deformation band of CH 3 is removed because of the increase of the reduced mass due to the immobilization of the chain between the oxygen atoms." @default.
- W2072694148 created "2016-06-24" @default.
- W2072694148 creator A5002425433 @default.
- W2072694148 creator A5011857679 @default.
- W2072694148 creator A5016471819 @default.
- W2072694148 creator A5038832864 @default.
- W2072694148 date "1969-12-01" @default.
- W2072694148 modified "2023-09-25" @default.
- W2072694148 title "Influence of the Van der Waals force on the infrared spectra of short aliphatic alkylammonium cations held on montmorillonite" @default.
- W2072694148 cites W1608530383 @default.
- W2072694148 cites W1964841415 @default.
- W2072694148 cites W1971812126 @default.
- W2072694148 cites W1995857352 @default.
- W2072694148 cites W1997283548 @default.
- W2072694148 cites W2000570667 @default.
- W2072694148 cites W2026698793 @default.
- W2072694148 cites W2028882686 @default.
- W2072694148 cites W2071564244 @default.
- W2072694148 cites W2324231466 @default.
- W2072694148 cites W2333748485 @default.
- W2072694148 cites W2897987659 @default.
- W2072694148 doi "https://doi.org/10.1180/claymin.1969.008.2.01" @default.
- W2072694148 hasPublicationYear "1969" @default.
- W2072694148 type Work @default.
- W2072694148 sameAs 2072694148 @default.
- W2072694148 citedByCount "25" @default.
- W2072694148 countsByYear W20726941482015 @default.
- W2072694148 countsByYear W20726941482016 @default.
- W2072694148 countsByYear W20726941482017 @default.
- W2072694148 countsByYear W20726941482020 @default.
- W2072694148 countsByYear W20726941482021 @default.
- W2072694148 countsByYear W20726941482022 @default.
- W2072694148 crossrefType "journal-article" @default.
- W2072694148 hasAuthorship W2072694148A5002425433 @default.
- W2072694148 hasAuthorship W2072694148A5011857679 @default.
- W2072694148 hasAuthorship W2072694148A5016471819 @default.
- W2072694148 hasAuthorship W2072694148A5038832864 @default.
- W2072694148 hasConcept C112887158 @default.
- W2072694148 hasConcept C120665830 @default.
- W2072694148 hasConcept C121332964 @default.
- W2072694148 hasConcept C125888099 @default.
- W2072694148 hasConcept C126061179 @default.
- W2072694148 hasConcept C1276947 @default.
- W2072694148 hasConcept C147789679 @default.
- W2072694148 hasConcept C150394285 @default.
- W2072694148 hasConcept C153642686 @default.
- W2072694148 hasConcept C158355884 @default.
- W2072694148 hasConcept C159467904 @default.
- W2072694148 hasConcept C178790620 @default.
- W2072694148 hasConcept C185592680 @default.
- W2072694148 hasConcept C2777335606 @default.
- W2072694148 hasConcept C2777515222 @default.
- W2072694148 hasConcept C32909587 @default.
- W2072694148 hasConcept C4839761 @default.
- W2072694148 hasConcept C540031477 @default.
- W2072694148 hasConcept C73683733 @default.
- W2072694148 hasConcept C8010536 @default.
- W2072694148 hasConceptScore W2072694148C112887158 @default.
- W2072694148 hasConceptScore W2072694148C120665830 @default.
- W2072694148 hasConceptScore W2072694148C121332964 @default.
- W2072694148 hasConceptScore W2072694148C125888099 @default.
- W2072694148 hasConceptScore W2072694148C126061179 @default.
- W2072694148 hasConceptScore W2072694148C1276947 @default.
- W2072694148 hasConceptScore W2072694148C147789679 @default.
- W2072694148 hasConceptScore W2072694148C150394285 @default.
- W2072694148 hasConceptScore W2072694148C153642686 @default.
- W2072694148 hasConceptScore W2072694148C158355884 @default.
- W2072694148 hasConceptScore W2072694148C159467904 @default.
- W2072694148 hasConceptScore W2072694148C178790620 @default.
- W2072694148 hasConceptScore W2072694148C185592680 @default.
- W2072694148 hasConceptScore W2072694148C2777335606 @default.
- W2072694148 hasConceptScore W2072694148C2777515222 @default.
- W2072694148 hasConceptScore W2072694148C32909587 @default.
- W2072694148 hasConceptScore W2072694148C4839761 @default.
- W2072694148 hasConceptScore W2072694148C540031477 @default.
- W2072694148 hasConceptScore W2072694148C73683733 @default.
- W2072694148 hasConceptScore W2072694148C8010536 @default.
- W2072694148 hasIssue "2" @default.
- W2072694148 hasLocation W20726941481 @default.
- W2072694148 hasOpenAccess W2072694148 @default.
- W2072694148 hasPrimaryLocation W20726941481 @default.
- W2072694148 hasRelatedWork W174761458 @default.
- W2072694148 hasRelatedWork W1991883810 @default.
- W2072694148 hasRelatedWork W2005831018 @default.
- W2072694148 hasRelatedWork W2322592617 @default.
- W2072694148 hasRelatedWork W2406017546 @default.
- W2072694148 hasRelatedWork W2905213303 @default.
- W2072694148 hasRelatedWork W2924720708 @default.
- W2072694148 hasRelatedWork W3015532053 @default.
- W2072694148 hasRelatedWork W3022296595 @default.
- W2072694148 hasRelatedWork W4288515275 @default.
- W2072694148 hasVolume "8" @default.
- W2072694148 isParatext "false" @default.
- W2072694148 isRetracted "false" @default.
- W2072694148 magId "2072694148" @default.
- W2072694148 workType "article" @default.