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• W2072734490 abstract "The chloro-bridged dimer [(PC)Pt(μ-Cl)]2 (PC = [(tBu2P-o-C6H4)-CMe2]−) reacts with silver(I) acetate to yield the monomeric κ2-acetate complex [(PC)Pt(κ2-OOCMe)]. Its trifluoroacetate analogue exists in solution as a mixture of the monomer and two isomeric dimers, and crystallizes as the approximately C2-symmetrical dimer [(PC)Pt(μ-OOCCF3)]2. NMR experiments and density functional theory calculations show that the monomeric species are favored by bulky ligands and electron-rich carboxylates. [(PC)Pt(OOCCF3)] undergoes a ligand-dehydrogenation reaction in hot trifluoroacetic acid to yield [(PCC)Pt(OOCCF3)2] (PCC = (tBu2P-o-C6H4)-C(Me)=CH2)." @default.
• W2072734490 created "2016-06-24" @default.
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• W2072734490 date "2009-06-23" @default.
• W2072734490 modified "2023-10-18" @default.
• W2072734490 title "Mononuclear Platinum(II) Complexes Incorporating κ²-Carboxylate Ligands: Synthesis, Structure, and Reactivity" @default.
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• W2072734490 doi "https://doi.org/10.1021/ic900677c" @default.
• W2072734490 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19548692" @default.
• W2072734490 hasPublicationYear "2009" @default.
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