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- W2072739145 abstract "Phosphonate complexes M(PPh3)2(I)(CH2P(O)(OR)2) (M = Pd and Pt, R = Me and Et) have been prepared by the oxidative addition of ICH2P(O)(OR)2 to M(PPh3)4. While the platinum product isomerized slowly from the cis- to the rans-isomer, the palladium compound decomposed in soluton. Several compounds have been identified from the decomposition reaction: ICH2P(O)(OCH3)2, CH3P(O)(OCH3)2, [Pd(PPh3)2(CH2P(O)(OCH3)2)]I, OPPh3 and [Pd(PPh3)(I)(CH2P(O)(OCH3)2)]2. In air, ICH2P(O)(OCH3)2 was the major product observed; however, in the absence of air, CH3P(O)(OCH3)2 was the major product. A study of the reaction pathway showed that the reductive elimination proceeded via phosphine dissociation. The structures of the trans- and cis-platinum compounds were determined by X-ray diffraction, and were refined to Rw = 0.036 (5382 observed reflections) and 0.027 (5274 observed reflections), respectively. The bond lengths of PtP, PtC and PtI trans to various ligands clearly demonstrate the order of the trans influence: phosphonate > phosphine > I." @default.
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- W2072739145 date "1986-01-01" @default.
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- W2072739145 title "Phosphonate complexes of palladium(II) and platinum(II): Oxidative addition and reductive elimination, the crystal and molecular structures of cis- and trans-[Pt(PPh3)2(I)(CH2P(O)(OCH3)2)]" @default.
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- W2072739145 doi "https://doi.org/10.1016/s0022-328x(00)99588-3" @default.
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