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• W2072743144 abstract "The reaction of [Ru(solvent)2(bpy)2]2+ (bpy = 2,2‘-bipyridine) with Haet (2-aminoethanethiol) in ethanol/water in the presence of Ag+ gave a thiolato-bridged RuIIAgIRuII trinuclear complex, [Ag{Ru(aet)(bpy)2}2]3+, in which two [RuII(aet)(bpy)2]+ units are linked by an AgI atom. When this complex was treated with HCl in acetonitrile/water, a disulfide-bridged RuIIRuII dinuclear complex, [Ru2(cysta)(bpy)4]4+ (cysta = cystamine), was produced as a result of the removal of an AgI atom and the autoxidation of thiolato groups. It was found that the dinuclear structure in [Ru2(cysta)(bpy)4]4+ is reverted back to [Ag{Ru(aet)(bpy)2}2]3+ by treatment with Ag+ assisted by Zn reduction." @default.
• W2072743144 created "2016-06-24" @default.
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• W2072743144 date "2007-07-17" @default.
• W2072743144 modified "2023-09-24" @default.
• W2072743144 title "Thiolato-Bridged Ru^IIAg^IRu^II Trinuclear Complex Composed of Bis(bipyridine)ruthenium(II) Units with Chelating 2-Aminoethanethiolate: Conversion to a Disulfide-Bridged Ru^IIRu^II Dinuclear Complex" @default.
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• W2072743144 doi "https://doi.org/10.1021/ic700572r" @default.
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