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- W2072783268 abstract "The metal-catalyzed oxidation of organic compounds with t-butyl hydroperoxide (TBHP) and Rh(PPh3)3 and Rh+(diphos) has been investigated. Under appropriate conditions both catalysts give identical results; anthracene is converted into anthraquinone, 1-octene into 2-octanone, and 1-phenylethanol into acetophenone, with 95 to 100% isolated yields. The phosphine ligands of the catalysts are rapidly attacked during the oxidations, but this does not decrease the activity of the catalytic system. The formation of 2-octanone from 1-octene is believed to be due to a metal-centered mechanism rather than to a free radical pathway. The same mechanism should apply to the oxidation of anthracene and 1-phenylethanol." @default.
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- W2072783268 date "1988-05-01" @default.
- W2072783268 modified "2023-09-29" @default.
- W2072783268 title "Rhodium-catalyzed oxidation of organic compounds with t-butyl hydroperoxide" @default.
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- W2072783268 doi "https://doi.org/10.1016/0022-328x(88)80247-x" @default.
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