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- W2072783805 abstract "T′-RE2CuO4 (RE: rare-earth element), after appropriate “reduction”, has fairly high conductivity and also exhibits clear Fermi edge in photoemission spectroscopy. To clarify the origin of conductivity in the T′ mother compounds, we evaluated the unscreened charge-transfer gap (Δ0) for T′-RE2CuO4 and T-La2CuO4. The Δ0 value for T′-compounds almost linearly decreases with increasing the ionic radius of RE from 12.24 eV for T′-Tm2CuO4 to 9.90 eV for T′-La2CuO4. The results qualitatively explain metallic conductivity in T′-RE2CuO4 for large RE." @default.
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- W2072783805 date "2006-10-01" @default.
- W2072783805 modified "2023-10-01" @default.
- W2072783805 title "Charge transfer gap for T′-RE2CuO4 and T-La2CuO4 as estimated from Madelung potential calculations" @default.
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- W2072783805 doi "https://doi.org/10.1016/j.physc.2006.03.087" @default.
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