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- W2072786104 abstract "The absence of the shielding effect of the phenyl ring in 2-phosphino-1,3-dithianes containing axial Ph(R)P(:) group (R= Me, Ph), as well an a large (7–8 Hz) coupling constant between axial phosphorus and carbons C(4,6) suggest the endo position of the phosphorus lone electron pair. The exo-anomeric effect, which could be governed by np-σ* c-s negative hyperconjugation is not manifested in this system. The observed rotational behavior can be sufficiently explained on steric grounds." @default.
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- W2072786104 date "1993-02-01" @default.
- W2072786104 modified "2023-09-23" @default.
- W2072786104 title "Lack of manifestation of the exo-anomeric effect in SCP(:) System" @default.
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- W2072786104 doi "https://doi.org/10.1016/s0040-4039(00)60335-0" @default.
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