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- W2072787581 abstract "The gas-phase pyrolysis of 1,2-dichloropropane has been studied at temperatures from 393 to 470°C and initial pressures from 0.2 to 26.0 Torr. In a 1-1. silica reaction vessel of low surface/volume ratio, the products are the four monochloropropenes and hydrogen chloride. Above 440°C the product ratios show only a small dependence on temperature and the relative amounts of the various isomers at 457°C are (expressed as percentage of the total chloropropenes), 3-chloropropene 63.6%, cis-1-chloropropene 22.9 %, trans-1-chloropropene 12.7 %, 2-chloropropene 0.8 %. The overall reaction is closely represented by the pressure change which leads to the overall rate-constant log10k(s–1)=(13.78 ±0.21)–(54 760 ±440)/4.576 T. Arrhenius parameters have been derived for each of the chloropropene products from the above expression and the product ratios at various temperatures (extrapolated to zero time)." @default.
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- W2072787581 date "1971-01-01" @default.
- W2072787581 modified "2023-10-14" @default.
- W2072787581 title "Gas-phase pyrolysis of 1,2-dichloropropane" @default.
- W2072787581 doi "https://doi.org/10.1039/tf9716700080" @default.
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