FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2072815345> ?p ?o ?g. }

• W2072815345 endingPage "1833" @default.
• W2072815345 startingPage "1827" @default.
• W2072815345 abstract "In this work, we propose an improvement of the classical Derjaguin-Broekhoff-de Boer (DBdB) theory for capillary condensation/evaporation in mesoporous systems. The primary idea of this improvement is to employ the Gibbs-Tolman-Koenig-Buff equation to predict the surface tension changes in mesopores. In addition, the statistical film thickness (so-called t-curve) evaluated accurately on the basis of the adsorption isotherms measured for the MCM-41 materials is used instead of the originally proposed t-curve (to take into account the excess of the chemical potential due to the surface forces). It is shown that the aforementioned modifications of the original DBdB theory have significant implications for the pore size analysis of mesoporous solids. To verify our improvement of the DBdB pore size analysis method (IDBdB), a series of the calcined MCM-41 samples, which are well-defined materials with hexagonally ordered cylindrical mesopores, were used for the evaluation of the pore size distributions. The correlation of the IDBdB method with the empirically calibrated Kruk-Jaroniec-Sayari (KJS) relationship is very good in the range of small mesopores. So, a major advantage of the IDBdB method is its applicability for small mesopores as well as for the mesopore range beyond that established by the KJS calibration, i.e., for mesopore radii greater than approximately 4.5 nm. The comparison of the IDBdB results with experimental data reported by Kruk and Jaroniec for capillary condensation/evaporation as well as with the results from nonlocal density functional theory developed by Neimark et al. clearly justifies our approach. Note that the proposed improvement of the classical DBdB method preserves its original simplicity and simultaneously ensures a significant improvement of the pore size analysis, which is confirmed by the independent estimation of the mean pore size by the powder X-ray diffraction method." @default.
• W2072815345 created "2016-06-24" @default.
• W2072815345 creator A5003300001 @default.
• W2072815345 creator A5028006288 @default.
• W2072815345 creator A5063945652 @default.
• W2072815345 creator A5065693067 @default.
• W2072815345 creator A5087886448 @default.
• W2072815345 date "2005-01-26" @default.
• W2072815345 modified "2023-10-14" @default.
• W2072815345 title "Improvement of the Derjaguin−Broekhoff−de Boer Theory for Capillary Condensation/Evaporation of Nitrogen in Mesoporous Systems and Its Implications for Pore Size Analysis of MCM-41 Silicas and Related Materials" @default.
• W2072815345 cites W1556618280 @default.
• W2072815345 cites W1964107229 @default.
• W2072815345 cites W1966798749 @default.
• W2072815345 cites W1978225236 @default.
• W2072815345 cites W1981177327 @default.
• W2072815345 cites W1988206963 @default.
• W2072815345 cites W1993284583 @default.
• W2072815345 cites W1996235813 @default.
• W2072815345 cites W2009716643 @default.
• W2072815345 cites W2017065820 @default.
• W2072815345 cites W2024610881 @default.
• W2072815345 cites W2025865501 @default.
• W2072815345 cites W2029087156 @default.
• W2072815345 cites W2029184831 @default.
• W2072815345 cites W2031117927 @default.
• W2072815345 cites W2032606636 @default.
• W2072815345 cites W2039030999 @default.
• W2072815345 cites W2039241045 @default.
• W2072815345 cites W2041488869 @default.
• W2072815345 cites W2042602209 @default.
• W2072815345 cites W2043614150 @default.
• W2072815345 cites W2050276885 @default.
• W2072815345 cites W2082419639 @default.
• W2072815345 cites W2088927752 @default.
• W2072815345 cites W2094201535 @default.
• W2072815345 cites W2095062440 @default.
• W2072815345 cites W2101146408 @default.
• W2072815345 cites W2103223104 @default.
• W2072815345 cites W2154425964 @default.
• W2072815345 cites W2312199777 @default.
• W2072815345 cites W2378634263 @default.
• W2072815345 cites W2488960176 @default.
• W2072815345 cites W2950046727 @default.
• W2072815345 cites W4232146911 @default.
• W2072815345 doi "https://doi.org/10.1021/la047645n" @default.
• W2072815345 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15723478" @default.
• W2072815345 hasPublicationYear "2005" @default.
• W2072815345 type Work @default.
• W2072815345 sameAs 2072815345 @default.
• W2072815345 citedByCount "39" @default.
• W2072815345 countsByYear W20728153452013 @default.
• W2072815345 countsByYear W20728153452015 @default.
• W2072815345 countsByYear W20728153452016 @default.
• W2072815345 countsByYear W20728153452017 @default.
• W2072815345 countsByYear W20728153452018 @default.
• W2072815345 countsByYear W20728153452019 @default.
• W2072815345 countsByYear W20728153452021 @default.
• W2072815345 countsByYear W20728153452022 @default.
• W2072815345 countsByYear W20728153452023 @default.
• W2072815345 crossrefType "journal-article" @default.
• W2072815345 hasAuthorship W2072815345A5003300001 @default.
• W2072815345 hasAuthorship W2072815345A5028006288 @default.
• W2072815345 hasAuthorship W2072815345A5063945652 @default.
• W2072815345 hasAuthorship W2072815345A5065693067 @default.
• W2072815345 hasAuthorship W2072815345A5087886448 @default.
• W2072815345 hasConcept C121332964 @default.
• W2072815345 hasConcept C147789679 @default.
• W2072815345 hasConcept C150394285 @default.
• W2072815345 hasConcept C150581940 @default.
• W2072815345 hasConcept C161790260 @default.
• W2072815345 hasConcept C178790620 @default.
• W2072815345 hasConcept C185498141 @default.
• W2072815345 hasConcept C185592680 @default.
• W2072815345 hasConcept C192562407 @default.
• W2072815345 hasConcept C199289684 @default.
• W2072815345 hasConcept C200093464 @default.
• W2072815345 hasConcept C61441594 @default.
• W2072815345 hasConcept C7082614 @default.
• W2072815345 hasConcept C82776694 @default.
• W2072815345 hasConcept C84351421 @default.
• W2072815345 hasConcept C8892853 @default.
• W2072815345 hasConcept C97355855 @default.
• W2072815345 hasConceptScore W2072815345C121332964 @default.
• W2072815345 hasConceptScore W2072815345C147789679 @default.
• W2072815345 hasConceptScore W2072815345C150394285 @default.
• W2072815345 hasConceptScore W2072815345C150581940 @default.
• W2072815345 hasConceptScore W2072815345C161790260 @default.
• W2072815345 hasConceptScore W2072815345C178790620 @default.
• W2072815345 hasConceptScore W2072815345C185498141 @default.
• W2072815345 hasConceptScore W2072815345C185592680 @default.
• W2072815345 hasConceptScore W2072815345C192562407 @default.
• W2072815345 hasConceptScore W2072815345C199289684 @default.
• W2072815345 hasConceptScore W2072815345C200093464 @default.
• W2072815345 hasConceptScore W2072815345C61441594 @default.
• W2072815345 hasConceptScore W2072815345C7082614 @default.
• W2072815345 hasConceptScore W2072815345C82776694 @default.
• W2072815345 hasConceptScore W2072815345C84351421 @default.
• W2072815345 hasConceptScore W2072815345C8892853 @default.

• next