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- W2072820921 abstract "The heat capacity of nickel tungstate (NiWO4) was measured over the temperature range 5 to 350 K by adiabatic calorimetry, and that of cobalt tungstate (CoWO4) from 5 to 550 K. Temperatures of maximum heat capacities for the antiferromagnetic anomalies in cobalt and nickel tungstates were (47.7±0.1) K and (59.80±0.05) K. Excess entropies associated with the antiferromagnetic anomalies were evaluated as R ln 2 (1.38 calth K−1 mol−1) for CoWO4 and R ln 3 (2.18 calth K−1 mol−1) for NiWO4 with the lattice heat capacities of the compounds approximated by that of ZnWO4. In addition, the heat capacity of CoWO4 showed a continuing excess heat capacity consistent with a Schottky anomaly from energy levels lying roughly 600 to 3400 calth mol−1 above the ground state. Selected thermal functions: Cpo, So, and −{Go(T)−Ho(0)}T at 298.15 K are respectively 28.41, 30.08, and 14.01 calth K−1 mol−1 for CoWO4, and 27.77, 28.51, and 13.21 calth K−1 mol−1 for NiWO4." @default.
- W2072820921 created "2016-06-24" @default.
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- W2072820921 date "1976-05-01" @default.
- W2072820921 modified "2023-09-25" @default.
- W2072820921 title "Thermophysical measurements on transitionmetal tungstates II. Heat capacities of antiferromagnetic nickel and cobalt tungstates" @default.
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- W2072820921 doi "https://doi.org/10.1016/0021-9614(76)90068-9" @default.
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