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• W2072824150 endingPage "12236" @default.
• W2072824150 startingPage "12230" @default.
• W2072824150 abstract "The thermodynamic hydride donor abilities of [HW(CO)5]- (40 kcal/mol), [HW(CO)4P(OMe3)]- (37 kcal/mol), and [HW(CO)4(PPh3)]- (36 kcal/mol) have been measured in acetonitrile by either equilibrium or calorimetric methods. The hydride donor abilities of these complexes are compared with other complexes for which similar thermodynamic measurements have been made. [HW(CO)5]-, [HW(CO)4P(OMe3)]-, and [HW(CO)4(PPh3)]- all react rapidly with [Cp*Re(PMe3)(NO)(CO)]+ to form dinuclear intermediates with bridging formyl ligands. These intermediates slowly form [Cp*Re(PMe3)(NO)(CHO)] and [W(CO)4(L)(CH3CN)]. The structure of cis-[HW(CO)4(PPh3)]- has been determined and has the expected octahedral structure. The hydride ligand bends away from the CO ligand trans to PPh3 and toward PPh3." @default.
• W2072824150 created "2016-06-24" @default.
• W2072824150 creator A5012168481 @default.
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• W2072824150 creator A5082146943 @default.
• W2072824150 creator A5083154209 @default.
• W2072824150 creator A5083751600 @default.
• W2072824150 date "2003-09-13" @default.
• W2072824150 modified "2023-10-14" @default.
• W2072824150 title "Thermodynamic Hydride Donor Abilities of [HW(CO)₄L]^- Complexes (L = PPh₃, P(OMe)₃, CO) and Their Reactions with [C₅Me₅Re(PMe₃)(NO)(CO)]⁺" @default.
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• W2072824150 doi "https://doi.org/10.1021/ja036524r" @default.
• W2072824150 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14519008" @default.
• W2072824150 hasPublicationYear "2003" @default.
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