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- W2072856076 abstract "[1.1.1]propellane reacts with tetracyanoethylene to give a 1:1 adduct having a 3-methylenecyclobutyl group spiro-fused to a tetracyanocyclopropane. The reaction with dimethyl acetylenedicarboxylate gave a 2:1 adduct, formed via an initial reaction such as found with tetracyanoethylene, followed by the reaction of the dicyanocyclopropene unit in the product with a second propellane. Bicyclo[1.1.0]butane is more reactive than the propellane, and in competition reactions, 1:1:1 adducts are formed." @default.
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- W2072856076 date "1987-01-01" @default.
- W2072856076 modified "2023-10-12" @default.
- W2072856076 title "[1.1.1]Propellane: Reaction with electron deficient alkenes and alkynes" @default.
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- W2072856076 doi "https://doi.org/10.1016/s0040-4039(00)95672-7" @default.
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