FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2072864770> ?p ?o ?g. }

• W2072864770 endingPage "44" @default.
• W2072864770 startingPage "37" @default.
• W2072864770 abstract "Confinement of a solution can slow solvent dynamics and in turn influence the reactivity and structure of the solute. Encapsulating a protein in an aqueous pore affects its binding properties, stability to degradation, interconversion between conformational states, and energy relaxation. We perform molecular dynamics simulations of H64V-CO mutant myoglobin solvated by varying amounts of liquid water, and in turn enclosed by a matrix of immobilized solvent, to mimic differing degrees of confinement of H64V-CO in a glass. We calculate the three-pulse vibrational echo signal of the CO ligand from the autocorrelation function of fluctuations in the CO vibrational frequency. When the first solvation layer alone is free to relax, the correlation function displays only fast relaxation reminiscent of the case of a protein in a fixed, immobilized solvent matrix. However the vibrational echo signal in this case decays significantly more rapidly than for a static solvent. With two solvation layers mobile, the correlation function displays long time relaxation characteristic of the unconfined protein and the echo signal decays rapidly. The echo signal of the protein with two mobile solvation layers is nearly identical to that of the unconfined protein, despite the substantially constrained solvent dynamics in the confined case." @default.
• W2072864770 created "2016-06-24" @default.
• W2072864770 creator A5018028564 @default.
• W2072864770 creator A5019215700 @default.
• W2072864770 date "2007-11-01" @default.
• W2072864770 modified "2023-10-18" @default.
• W2072864770 title "Dephasing dynamics in confined myoglobin" @default.
• W2072864770 cites W1518327983 @default.
• W2072864770 cites W1618739094 @default.
• W2072864770 cites W1966165983 @default.
• W2072864770 cites W1970979585 @default.
• W2072864770 cites W1976481362 @default.
• W2072864770 cites W1986146518 @default.
• W2072864770 cites W2000661497 @default.
• W2072864770 cites W2001801265 @default.
• W2072864770 cites W2001804099 @default.
• W2072864770 cites W2003440615 @default.
• W2072864770 cites W2007800651 @default.
• W2072864770 cites W2010959064 @default.
• W2072864770 cites W2013287648 @default.
• W2072864770 cites W2017644006 @default.
• W2072864770 cites W2020904151 @default.
• W2072864770 cites W2021332158 @default.
• W2072864770 cites W2023440735 @default.
• W2072864770 cites W2025029119 @default.
• W2072864770 cites W2029724676 @default.
• W2072864770 cites W2039929450 @default.
• W2072864770 cites W2042953791 @default.
• W2072864770 cites W2045211165 @default.
• W2072864770 cites W2045598937 @default.
• W2072864770 cites W2050362762 @default.
• W2072864770 cites W2054134130 @default.
• W2072864770 cites W2054135984 @default.
• W2072864770 cites W2058006670 @default.
• W2072864770 cites W2058097108 @default.
• W2072864770 cites W2060227993 @default.
• W2072864770 cites W2060872711 @default.
• W2072864770 cites W2066196541 @default.
• W2072864770 cites W2072225167 @default.
• W2072864770 cites W2073690435 @default.
• W2072864770 cites W2086430333 @default.
• W2072864770 cites W2091281674 @default.
• W2072864770 cites W2098500343 @default.
• W2072864770 cites W2101357626 @default.
• W2072864770 cites W2109467211 @default.
• W2072864770 cites W2114577816 @default.
• W2072864770 cites W2130119647 @default.
• W2072864770 cites W2130479394 @default.
• W2072864770 cites W2132397429 @default.
• W2072864770 cites W2134464060 @default.
• W2072864770 cites W2152471118 @default.
• W2072864770 cites W2152977647 @default.
• W2072864770 cites W2170970354 @default.
• W2072864770 cites W2761165217 @default.
• W2072864770 doi "https://doi.org/10.1016/j.chemphys.2007.04.001" @default.
• W2072864770 hasPublicationYear "2007" @default.
• W2072864770 type Work @default.
• W2072864770 sameAs 2072864770 @default.
• W2072864770 citedByCount "3" @default.
• W2072864770 countsByYear W20728647702012 @default.
• W2072864770 crossrefType "journal-article" @default.
• W2072864770 hasAuthorship W2072864770A5018028564 @default.
• W2072864770 hasAuthorship W2072864770A5019215700 @default.
• W2072864770 hasConcept C121332964 @default.
• W2072864770 hasConcept C147597530 @default.
• W2072864770 hasConcept C147789679 @default.
• W2072864770 hasConcept C148093993 @default.
• W2072864770 hasConcept C15744967 @default.
• W2072864770 hasConcept C159467904 @default.
• W2072864770 hasConcept C178790620 @default.
• W2072864770 hasConcept C184651966 @default.
• W2072864770 hasConcept C185592680 @default.
• W2072864770 hasConcept C2775981520 @default.
• W2072864770 hasConcept C2776029896 @default.
• W2072864770 hasConcept C2778063876 @default.
• W2072864770 hasConcept C2780471494 @default.
• W2072864770 hasConcept C49023278 @default.
• W2072864770 hasConcept C59593255 @default.
• W2072864770 hasConcept C62520636 @default.
• W2072864770 hasConcept C77805123 @default.
• W2072864770 hasConceptScore W2072864770C121332964 @default.
• W2072864770 hasConceptScore W2072864770C147597530 @default.
• W2072864770 hasConceptScore W2072864770C147789679 @default.
• W2072864770 hasConceptScore W2072864770C148093993 @default.
• W2072864770 hasConceptScore W2072864770C15744967 @default.
• W2072864770 hasConceptScore W2072864770C159467904 @default.
• W2072864770 hasConceptScore W2072864770C178790620 @default.
• W2072864770 hasConceptScore W2072864770C184651966 @default.
• W2072864770 hasConceptScore W2072864770C185592680 @default.
• W2072864770 hasConceptScore W2072864770C2775981520 @default.
• W2072864770 hasConceptScore W2072864770C2776029896 @default.
• W2072864770 hasConceptScore W2072864770C2778063876 @default.
• W2072864770 hasConceptScore W2072864770C2780471494 @default.
• W2072864770 hasConceptScore W2072864770C49023278 @default.
• W2072864770 hasConceptScore W2072864770C59593255 @default.
• W2072864770 hasConceptScore W2072864770C62520636 @default.
• W2072864770 hasConceptScore W2072864770C77805123 @default.
• W2072864770 hasIssue "1-3" @default.

• next