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- W2072877818 abstract "The suitability of micro-liquid chromatography (micro-LC) (liquid chromatography on packed fused-silica capillary columns) for enantiomer separations was demonstrated for bovine serum albumin (BSA)-coated silica gel. Micro-LC has the great advantage of needing only very small amounts of possibly very expensive chiral stationary phases. The elution order for a series of N-nitroaroylamino acids on BSA-coated silica gel was determined. Column overload effects on BSA-coated silica gel occur at much lower concentrations than on other stationary phases. These overload effects result in strange retention time shifts whereby the later eluting peak is mostly affected. The resulting large selectivity change with sample size is unusual in LC. An explanation is attempted." @default.
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- W2072877818 date "1988-01-01" @default.
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- W2072877818 title "Micro-liquid chromatography and the chiral recognition mechanism on albumin-coated silica gel Large selectivity changes with sample size" @default.
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- W2072877818 doi "https://doi.org/10.1016/0021-9673(88)90039-8" @default.
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