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• W2072880810 abstract "Abstract Titration of Ru 3 (μ-H,μ-O=C(CH 3 )}(CO) 10 ( 1 ) with LiCH 3 in diethyl ether at − 30°C leads to its instantaneous conversion into [Li][Ru 3 {η 2 -C(CO)CH 3 }{μ-H,μ-O=C(CH 3 )}(CO) 9 ]. Alkylation with C 2 H 5 OSO 2 CF 3 at 25°C leads after 48 h to Ru 3 {μ-H 2 ,η 2 ,μ 3 -C(OEt)=C(H)}(CO) 9 ( 3 ) in 80% yield; acetaldehyde is obtained as a by-product. Use of LiCD 3 in the first step of this sequence gives unlabeled acetaldehyde and the trinuclear product Ru 3 {μ-D 2 ,η 2 ,μ 3 -C(OEt)=C(D)}(CO) 9 . Starting with Ru 3 {μ-H,μ-C(O)CD 3 }(CO) 10 and LiCH 3 , the reaction gives CD 3 C(O)H and no deuterium incorporation into the triruthenium product. Under an atmosphere of CO, acetaldehyde is still eliminated from the initial alkylation product but oxidative addition is prevented; IR spectroscopy indicates that a new complex is present, but this has eluded characterization owing to tis rapid conversion to 3 under conditions used in attempts to isolate or purify it. Reaction of 1 with LiPh or LiCMe 3 followed by alkylation with C 2 H 5 OSO 2 CF 3 also gives 3 , along with the corresponding aldehyde RC(O)H. Reaction of 1 with HNMe 2 followed by alkylation with C 2 H 5 OSO 2 CF 3 gives Ru 3 {μ-H 2 ,η 2 ,μ 3 -C(OEt)N(Me)C(H)}(CO) 9 (45% yield)." @default.
• W2072880810 created "2016-06-24" @default.
• W2072880810 creator A5002684641 @default.
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• W2072880810 date "1987-08-01" @default.
• W2072880810 modified "2023-09-24" @default.
• W2072880810 title "Double oxidative addition of CH bonds on a triruthenium cluster complex; synthesis and characterization of Ru3{μ-H2,η2,μ3-C(OEt)=C(H)}(CO)9 and Ru3{μ-H2,η2,μ3-C(OEt)N(Me)C(CH)}(CO)9" @default.
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• W2072880810 doi "https://doi.org/10.1016/0022-328x(87)80283-8" @default.
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