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- W2072881982 abstract "Mercury-plated as well as bare nitrogenated diamond-like carbon (NDLC) microelectrode arrays have been investigated for application in in-situ determination of heavy metals (Cu, Pb and Cd) by differential pulse anodic stripping voltammetry (DPASV). A microelectrode array consisting of 50 625 microdiscs with 3 μm in diameter and interelectrode distances of 20 μm was fabricated on a highly conductive silicon substrate and characterized by CV measurements. Current responses of all metals were linear for metal concentrations in the range of 1.6 × 10−8 to 8.3 × 10−8 mol/L and preconcentration time 5 min. The stripping current responses of the bare microelectrode array reached under the same conditions were much lower in comparison with a mercury-plated array. A strong effect upon stripping current responses of metals was observed of adding a small amount of thiocyanate (2 × 10−3 mol/L) into the plating solution." @default.
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- W2072881982 date "2007-04-01" @default.
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- W2072881982 title "Determination of heavy metals by a mercury-plated diamondlike carbon microelectrode array" @default.
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- W2072881982 doi "https://doi.org/10.1088/1742-6596/61/1/194" @default.
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