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- W2072885846 abstract "Abstract The temperature dependence of the adsorption of deoxyribonucleic acid at the mercury | electrolyte interface has been investigated using a.c. polarography. The differential double layer capacitance was measured at the interface of a hanging mercury drop electrode in contact with a buffered aqueous solution of NaCl containing DNA. The potential of the rounded wave of the differential capacitance vs. potential plots in the presence of both native and denatured DNA does not depend on the temperature. This is in agreement with the well known fact that the adsorption of macromolecules is only slightly dependent on temperature. Conversely, the sharp wave is shifted to more positive potentials with increasing temperature. The decrease of the tendency to association of the adsorbed DNA molecules supporting the adsorption should be the cause of this shift. Several interface reactions were identified on the basis of the dependence on time of the differential capacitance at different potentials and temperatures. The reasons for these reactions have been discussed." @default.
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- W2072885846 date "1975-01-01" @default.
- W2072885846 modified "2023-09-25" @default.
- W2072885846 title "On the adsorption of DNA at the mercury-electrolyte interface. IV. Temperature dependence of the reactions of DNA at the mercury electrolyte interface" @default.
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- W2072885846 doi "https://doi.org/10.1016/0302-4598(75)80009-2" @default.
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