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- W2072886070 abstract "Polymerizations of ethylene or propylene were conducted in toluene employing the soluble catalytic system TiCl4. THF/AlCl2(C2H5)/Al(i-C4H9)3 combined with different metal chlorides (CoCl2,MgCl2 or ZnCl2) complexed with tetrahydrofuran (THF). The catalyst activity was strongly dependent upon the metal chloride used as modifier. A clear increase of catalyst activity in ethylene polymerization was observed when the Co/Ti or Mg/Ti mole ratio was increased up to 2 and then decreased markedly. In a similar way, the catalyst activity in propylene polymerization was strongly dependent upon the amount and kind of metal chloride used as modifier." @default.
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- W2072886070 date "1995-01-01" @default.
- W2072886070 modified "2023-10-17" @default.
- W2072886070 title "Preparation of soluble TiCl4 catalyst modified with some metal chlorides and its use for ethylene and propylene homopolymerization" @default.
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- W2072886070 doi "https://doi.org/10.1016/0032-3861(95)90695-x" @default.
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