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- W2072891856 abstract "Both the regioselectivity and the reaction rate for the β-cyclodextrin (β-CyD)-induced P–O(3′) cleavage of adenosine 2′, 3′-cyclic phosphate (A > p) to adenosine 2′-phosphate are greatly promoted by KF. The promoting activity of KF is much larger than that of KCl. KF amplifies the difference in the chemical circumstance between the P–O(2′) and the P–O(3′) bonds of A > p, induced by β-CyD on complex formation with A > p. The higher activity of KF is ascribed to absence of complex formation of F− ion with β-CyD, which results in deeper penetration of A > p into the cavity of β-CyD." @default.
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- W2072891856 date "1992-08-01" @default.
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- W2072891856 title "Potassium fluoride for the promotion of ?-cyclodextrin-induced regioselective P?O(3?) cleavage of adenosine 2?, 3?-cyclic phosphate" @default.
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- W2072891856 doi "https://doi.org/10.1002/poc.610050812" @default.
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