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• W2072904332 abstract "The first total synthesis of a heptasaccharide found in the iron-binding exopolysaccharide produced by Klebsiella oxytoca BAS-10 has been achieved in excellent yield using a block synthetic strategy. A trisaccharide glycosyl donor was stereoselectively coupled with a tetrasaccharide glycosyl acceptor using the trichloroacetimidate activation procedure. The yields and stereo outcome were excellent in each step of glycosylation. A late stage oxidation protocol was adopted for the oxidation of the primary hydroxyl group to the carboxylic functionality while keeping a secondary hydroxyl group unaffected." @default.
• W2072904332 created "2016-06-24" @default.
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• W2072904332 date "2009-08-01" @default.
• W2072904332 modified "2023-10-18" @default.
• W2072904332 title "Total synthesis of the heptasaccharide repeating unit of the iron-binding exopolysaccharide secreted by Klebsiella oxytoca BAS-10" @default.
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• W2072904332 doi "https://doi.org/10.1016/j.tetasy.2009.07.009" @default.
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