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- W2072912041 abstract "The local structure and the g factors for the tetragonal Er3+ center in ThO2 are theoretically studied from the perturbation formulas of the g factors for a 4f11 ion in tetragonal symmetry. This defect center can be attributed to the substitutional Er3+ associated with a positive compensator in the center of the adjacent cube along the [1 0 0] direction. The four oxygen ions within the layer between the impurity Er3+ and the compensator are found to displace by about 0.18 Å towards the compensator due to their electrostatic attraction. The calculated g factors show reasonable agreement with the observed values. The validity of the assignment of the positive compensator is also discussed." @default.
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- W2072912041 date "2008-02-01" @default.
- W2072912041 modified "2023-09-22" @default.
- W2072912041 title "Studies on the local structure and the g factors for the tetragonal Er3+ center in ThO2" @default.
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- W2072912041 doi "https://doi.org/10.1016/j.jallcom.2007.04.165" @default.
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