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- W2072914294 abstract "ESR results for γ-irradiated K3[Co(CN)6] in powder and single crystal forms are reported. The main paramagnetic species detected at 77 K were diisocyanide [CoII(CN)4(NC)2]4− and pentacyanocobaltate (II) [CoII(CN)5]3−. On annealing, diisocyanide was lost and pentacyanocobaltate was formed. In Part I the reaction mechanism is discussed from the results of the powdered sample and in Part II the noncollinear structure is presented as the plausible molecular form of diisocyanide from the results of the single crystal." @default.
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- W2072914294 date "1976-07-01" @default.
- W2072914294 modified "2023-09-25" @default.
- W2072914294 title "ESR Study of γ-Ray Irradiated Potassium Hexacyanocobaltate K<sub>3</sub>[Co(CN)<sub>6</sub>]" @default.
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- W2072914294 doi "https://doi.org/10.1246/bcsj.49.1740" @default.
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