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- W2072932676 abstract "Abstract The effect of vibrational l -type doubling upon levels of C 2 H 2 in which both perpendicular modes ν 4 and ν 5 are excited complicates the evaluation of the vibrational interaction constants x 45 and g 45 . Previous experimental determinations of these two constants have neglected the effect of vibrational l -type doubling and hence assumed r 45 = 0. In the present work, combining the observational data obtained for the vibration rotation bands in the infrared with the measurements made in the far ultraviolet on the electronic bands of acetylene and using the current theory dealing with the problem of vibrational l -type doubling, an attempt has been made to obtain values for r 45 , x 45 , and g 45 . The newly determined x 45 and g 45 differ significantly from those derived by assuming r 45 = 0." @default.
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- W2072932676 date "1965-10-01" @default.
- W2072932676 modified "2023-09-27" @default.
- W2072932676 title "Infrared absorption bands of acetylene" @default.
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- W2072932676 doi "https://doi.org/10.1016/0022-2852(65)90071-8" @default.
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