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- W2072933384 abstract "Abstract Quaternary Li-Mn-V-O spinels were prepared by heating mixtures of MnCO 3 , V 2 O 5 and LiNO 3 at 700 °C for 36 h in air. The spinel oxides were characterized by X-ray diffraction, FT-IR spectroscopic, density and electrochemical measurements. The unit cell volume in a cubic cell increased with an increase in V content in LiV x Mn 2 − x O 4 ( x = 0–0.2), while the amounts of lithium intercalated into the spinels in a high potential region around 4 V versus Li/Li + decreased considerably with an increase in V content. Furthermore, the thermodynamics and kinetics of the lithium intercalation process into the spinel Li n V x Mn 2 − x O 4 were studied. The standard free energies of lithium intercalation into the spinels were −291 kJ/mol for x = 0 and −264 kJ/mol for x = 0.05 at n = 0–1 and 25 °C. The chemical and self-diffusion coefficients for lithium in Li n V x Mn 2 − x O 4 spinels were measured as functions of the n and x values by a current-pulse relaxation method. The diffusion coefficients in the spinel with x = 0.05 in the n -value range from 0.3 to 1 were about one order of magnitude lower than that in Li n Mn 2 O 4 ." @default.
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- W2072933384 date "1997-10-01" @default.
- W2072933384 modified "2023-09-24" @default.
- W2072933384 title "Preparation and electrochemical characteristics of quaternary Li-Mn-V-O spinel as the positive materials for rechargeable lithium batteries" @default.
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- W2072933384 doi "https://doi.org/10.1016/s0378-7753(96)02569-4" @default.
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