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- W2072938206 abstract "Hydrodynamic chromatography (HDC) of linear random coil polymers in columns packed with 1.5-μm non-porous particles was investigated. For polymers with high molecular masses (104-107), the resolution appears to be almost independent of the eluent velocity. This allows for high-speed polymer separations with high efficiency. A model for the migration rate of polymers, based on the assumption that interstitial channels in a packed column can be represented by a bundle of capillary tubes, is compared with experimental elution data. The influence of polymer size and type, solvent goodness and mobile phase velocity on elution in HDC was investigated. Elution behaviour in packed columns appears to obey basically the simple migration theories developed for open tubes. The relative peak positions in the HDC trace depend slightly on the eluent velocity." @default.
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- W2072938206 date "1993-12-01" @default.
- W2072938206 modified "2023-09-23" @default.
- W2072938206 title "Hydrodynamic chromatography of polymers in packed columns" @default.
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- W2072938206 doi "https://doi.org/10.1016/0021-9673(93)80285-g" @default.
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