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- W2072940269 abstract "Abstract Trithiazyltrichloride, (NSCl)3, reacted with [Ru(η-C5H5)2], [[Ru(cod)Cl2]x] (cod = cis-cis-1,5-cyclooctadiene), [Ru(cht)Cl2]2 (cht = 1,3,5-cycloheptatriene) and [(η6-C6H6)RuCl2]2 to give thionitrosyl complexes [(η5-C5H5)Ru(NS)Cl2], [Ru(NS)Cl2(cod)]Cl, [Ru(NS)Cl2(cht)]Cl and [(η6−C6H6)Ru(NS)Cl2]Cl, respectively. Reaction of nitrosyl chloride with [Ru(η5−C5H5)2], [Ru(cod)Cl2]x], [Ru(cht)Cl2]2 and [(η6-C6H6)RuCl2]2 yielded corresponding nitrosyl complexes [(η5-C5H5)Ru(NO)Cl2], [Ru(NO)Cl[in2(cod)]Cl, [Ru(NO)Cl2(cht)]Cl and [(η6-C6H6)Ru(NO)Cl2]Cl. The complex [(η6-C5H5)Ru(NO)Cl2] was also prepared by the reaction of Ru(NO)Cl3 with C5H6. In the presence of zinc dust, reaction of Ru(NO)Cl3 with C5H6 gave a paramagnetic complex [[(η5-C5H5)Ru(NO)]2(μ-Cl)2]." @default.
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- W2072940269 date "1995-07-01" @default.
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- W2072940269 title "Organometallic thionitrosyl and nitrosyl complexes of ruthenium" @default.
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- W2072940269 doi "https://doi.org/10.1016/0277-5387(94)00454-m" @default.
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