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- W2072963145 abstract "Novel MgCl2-supported Ziegler-Natta (Z-N) catalysts prepared using a new one-pot ball milling method can effectively control the amounts of Ti-loading in the catalysts. Complex GPC data on polypropylene synthesized by these novel catalysts were analyzed using the method of fitting the molecular weight distribution (MWD) curves with a multiple Flory-Schulz function. It was found that multiple active centers exist in these novel catalysts. Detailed study of the effects of the Ti-loadings in the catalysts on the distribution of the active centers showed that the Ti-loadings in the novel MgCl2-supported Z-N catalysts might affect the proportion of each type of active centers; and might be the main factor responsible for the effect of the Ti-loadings on the microstructure, the molecular weight and molecular weight distribution width of the resultant polymer, the catalytic activity and polymerization kinetics." @default.
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- W2072963145 date "2004-08-01" @default.
- W2072963145 modified "2023-09-24" @default.
- W2072963145 title "Study on the distribution of active centers in novel low Ti-loading MgCl2-supported Ziegler-Natta catalyst." @default.
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- W2072963145 doi "https://doi.org/10.1007/bf02947597" @default.
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