Matches in SemOpenAlex for { <https://semopenalex.org/work/W2072996444> ?p ?o ?g. }
- W2072996444 endingPage "4320" @default.
- W2072996444 startingPage "4312" @default.
- W2072996444 abstract "A high surface area 3D ordered SnO2 inverted opal with walls composed of interconnected nanocrystals is reported using a facile approach with tin acetate precursors. The hierarchically porous structure exhibits porosity on multiple lengths scales (cm down to nm). The thickness of the IO wall structure comprising nanocrystals of the oxide can be tuned by multiple infilling of the precursor. Using highly monodisperse Pd nanoparticles, we show how the SnO2 IO can be functionalized with immobilized Pd NP assemblies. We show that the Pd NP size dispersion is controlled by utilizing weak ligand–metal interactions and strong metal-oxide interactions for the immobilization step. The resulting SnO2–Pd IOs were investigated X-ray photoelectron spectroscopy indicating electronic interactions between the Pd and SnO2 and alterations to NP surface chemistry. Pd NPs assembled with excellent dispersion on the ordered SnO2 IOs show superior catalytic performance for liquid phase chemical synthesis via Suzuki coupling reactions and allow easy removal of the catalyst substrate post reaction. Higher mass electrocatalytic activity is also demonstrated for formic acid oxidation, compared to commercial Pd/C catalysts, which is shown to be due to better access to the catalytically active sites on SnO2–Pd IOs. The high surface area interconnected phase-pure SnO2 IO, with programmable porosity forms a functional material for catalytic applications." @default.
- W2072996444 created "2016-06-24" @default.
- W2072996444 creator A5001195284 @default.
- W2072996444 creator A5042727501 @default.
- W2072996444 creator A5075707605 @default.
- W2072996444 creator A5082545871 @default.
- W2072996444 creator A5087678469 @default.
- W2072996444 creator A5090178296 @default.
- W2072996444 date "2013-10-29" @default.
- W2072996444 modified "2023-09-30" @default.
- W2072996444 title "Three-Dimensionally Ordered Hierarchically Porous Tin Dioxide Inverse Opals and Immobilization of Palladium Nanoparticles for Catalytic Applications" @default.
- W2072996444 cites W1480859926 @default.
- W2072996444 cites W1964428441 @default.
- W2072996444 cites W1968380495 @default.
- W2072996444 cites W1969745158 @default.
- W2072996444 cites W1976755207 @default.
- W2072996444 cites W1977802928 @default.
- W2072996444 cites W1978726185 @default.
- W2072996444 cites W1986356581 @default.
- W2072996444 cites W1987665052 @default.
- W2072996444 cites W1988169437 @default.
- W2072996444 cites W1992257934 @default.
- W2072996444 cites W1996369752 @default.
- W2072996444 cites W1996705260 @default.
- W2072996444 cites W2002551418 @default.
- W2072996444 cites W2007084362 @default.
- W2072996444 cites W2009668040 @default.
- W2072996444 cites W2010980873 @default.
- W2072996444 cites W2014494345 @default.
- W2072996444 cites W2014578664 @default.
- W2072996444 cites W2019072240 @default.
- W2072996444 cites W2022921030 @default.
- W2072996444 cites W2023372234 @default.
- W2072996444 cites W2024383637 @default.
- W2072996444 cites W2026868387 @default.
- W2072996444 cites W2026949761 @default.
- W2072996444 cites W2027257650 @default.
- W2072996444 cites W2029687732 @default.
- W2072996444 cites W2030419782 @default.
- W2072996444 cites W2032448868 @default.
- W2072996444 cites W2034672716 @default.
- W2072996444 cites W2036791313 @default.
- W2072996444 cites W2039993483 @default.
- W2072996444 cites W2042424702 @default.
- W2072996444 cites W2043314504 @default.
- W2072996444 cites W2044293304 @default.
- W2072996444 cites W2049738552 @default.
- W2072996444 cites W2052051931 @default.
- W2072996444 cites W2063630257 @default.
- W2072996444 cites W2063731403 @default.
- W2072996444 cites W2066433725 @default.
- W2072996444 cites W2069200721 @default.
- W2072996444 cites W2070964442 @default.
- W2072996444 cites W2072324889 @default.
- W2072996444 cites W2073759728 @default.
- W2072996444 cites W2074833896 @default.
- W2072996444 cites W2086734201 @default.
- W2072996444 cites W2090452985 @default.
- W2072996444 cites W2090485890 @default.
- W2072996444 cites W2090608765 @default.
- W2072996444 cites W2112305783 @default.
- W2072996444 cites W2116475544 @default.
- W2072996444 cites W2118155234 @default.
- W2072996444 cites W2125044103 @default.
- W2072996444 cites W2128554180 @default.
- W2072996444 cites W2140440931 @default.
- W2072996444 cites W2140969134 @default.
- W2072996444 cites W2144823090 @default.
- W2072996444 cites W2144902715 @default.
- W2072996444 cites W2152374835 @default.
- W2072996444 cites W2154058146 @default.
- W2072996444 cites W2163896356 @default.
- W2072996444 cites W2165156510 @default.
- W2072996444 cites W2314665415 @default.
- W2072996444 cites W2329124836 @default.
- W2072996444 cites W2333953315 @default.
- W2072996444 doi "https://doi.org/10.1021/cm402458v" @default.
- W2072996444 hasPublicationYear "2013" @default.
- W2072996444 type Work @default.
- W2072996444 sameAs 2072996444 @default.
- W2072996444 citedByCount "74" @default.
- W2072996444 countsByYear W20729964442014 @default.
- W2072996444 countsByYear W20729964442015 @default.
- W2072996444 countsByYear W20729964442016 @default.
- W2072996444 countsByYear W20729964442017 @default.
- W2072996444 countsByYear W20729964442018 @default.
- W2072996444 countsByYear W20729964442019 @default.
- W2072996444 countsByYear W20729964442020 @default.
- W2072996444 countsByYear W20729964442021 @default.
- W2072996444 countsByYear W20729964442022 @default.
- W2072996444 countsByYear W20729964442023 @default.
- W2072996444 crossrefType "journal-article" @default.
- W2072996444 hasAuthorship W2072996444A5001195284 @default.
- W2072996444 hasAuthorship W2072996444A5042727501 @default.
- W2072996444 hasAuthorship W2072996444A5075707605 @default.
- W2072996444 hasAuthorship W2072996444A5082545871 @default.
- W2072996444 hasAuthorship W2072996444A5087678469 @default.
- W2072996444 hasAuthorship W2072996444A5090178296 @default.