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- W2073005202 abstract "It is shown that fluorescence yield (FY) detection does not measure a pure X-ray absorption spectrum if multiplet effects are important. The reason is that while the Auger decay is approximately constant, the fluorescence decay shows a strong dependence on the final state. With a coherent description of the X-ray absorption and X-ray emission processes, the observed differences between TEY and FY detected nickel 2p edges can be reproduced accurately. In the, approximate, incoherent description the FY spectral shape identifies with the X-ray absorption spectrum multiplied with its state dependent fluorescence decay. Self-absorption effects are calculated and the implications for X-ray Magnetic Circular Dichroism (X-MCD) and generalisations to other systems are discussed." @default.
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- W2073005202 date "1994-12-01" @default.
- W2073005202 modified "2023-10-16" @default.
- W2073005202 title "Fluorescence yield detection: Why it does not measure the X-ray absorption cross section" @default.
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- W2073005202 doi "https://doi.org/10.1016/0038-1098(94)90027-2" @default.
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