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- W2073017265 abstract "The reactions of zinc oxide with α-Fe2O3 and with γ-Fe2O3 leading to the formation of zinc ferrite (ZnFe2O4) have been studied at different partial pressures of oxygen in the temperature range 500–800°C. The ferrite spinel is formed more readily when γ-Fe2O3 is used as the reactant. The DTA and X-ray diffraction results indicate that the γ-Fe2O3 phase is stabilized in presence of ZnO. The lowering of partial pressure of oxygen in the ambient atmosphere favours the formation of zinc ferrite, indicating a cyclic redox process featuring Fe3+, Fe2+ and oxygen at the phase boundaries. At very low oxygen pressures, conversion to zinc ferrite is not facilitated, apparently due to the formation of an intermediate species, Fe3−xZnxO4, which, under these conditions, is not easily converted to ZnFe2O4." @default.
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- W2073017265 date "1974-03-01" @default.
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- W2073017265 title "Studies on the formation of zinc ferrite" @default.
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- W2073017265 doi "https://doi.org/10.1016/0022-1902(74)80115-6" @default.
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