Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073024893> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2073024893 endingPage "161" @default.
- W2073024893 startingPage "152" @default.
- W2073024893 abstract "The use of micelle polymers, a class of polysoaps with a polymerized hydrophobic interior and a charged hydrophillic exterior, as pseudostationary phases in electrokinetic chromatography has generated significant interest. Their stable structure has been shown to provide significant advantages over conventional micelles when used as pseudostationary phases. In previous studies, micelle polymers have had carboxylate and sulfate head groups. These chemistries have limitations: carboxylate micelle polymers precipitate out of solution at pH less than seven or eight and sulfate head groups are not stable to hydrolysis and are hydrolyzed during polymerization. Additionally, while the chemical selectivity of conventional micelles varies with head group chemistry, no significant differences in chemical selectivity were observed between analogous polymers with sulfate and carboxylate groups. To overcome the limitations of carboxylate and sulfate head groups, and to further investigate the chemical selectivity of micelle polymers, poly(sodium-N-undec-10-ene-1-oyl-taurate) and poly(sodium-N-undec-10-ene-1-oyl-ethyl-2-phosphonate) micellar polymers have been synthesized and characterized as pseudostationary phases. These polymers have amide functionality and stable, strongly acidic sulfonate and phosphonate head groups. These polymers did provide improved solubility at low pH, and are stable under the conditions studied. The chromatographic performance and chemical selectivity of the polymers has been studied by several methods, including linear solvation energy relationships. Poly(sodiumN-undec-10-ene-1-oyl-taurate) has greater electrophoretic mobility than other polymers of this type, and can be used for the separation of hydrophobic compounds. The polymers do exhibit unique selectivity, but the differences in selectivity are not significant for the majority of compounds studied." @default.
- W2073024893 created "2016-06-24" @default.
- W2073024893 creator A5056944346 @default.
- W2073024893 creator A5077860652 @default.
- W2073024893 date "1999-01-01" @default.
- W2073024893 modified "2023-10-13" @default.
- W2073024893 title "Polymers of sodium-N-undec-10-ene-1-oyl taurate and sodium-N-undec-10-ene-1-oyl aminoethyl-2-phosphonate as pseudostationary phases for electrokinetic chromatography" @default.
- W2073024893 cites W1785606537 @default.
- W2073024893 cites W1967441316 @default.
- W2073024893 cites W1978400551 @default.
- W2073024893 cites W1981380778 @default.
- W2073024893 cites W1987841674 @default.
- W2073024893 cites W1987929839 @default.
- W2073024893 cites W2008912862 @default.
- W2073024893 cites W2009374012 @default.
- W2073024893 cites W2023402851 @default.
- W2073024893 cites W2024393106 @default.
- W2073024893 cites W2027150796 @default.
- W2073024893 cites W2030278594 @default.
- W2073024893 cites W2034438861 @default.
- W2073024893 cites W2035637823 @default.
- W2073024893 cites W2052060281 @default.
- W2073024893 cites W2054082457 @default.
- W2073024893 cites W2063041516 @default.
- W2073024893 cites W2068459463 @default.
- W2073024893 cites W2078668828 @default.
- W2073024893 cites W2080119698 @default.
- W2073024893 cites W2090941866 @default.
- W2073024893 cites W2095229834 @default.
- W2073024893 cites W2156347272 @default.
- W2073024893 cites W2160504440 @default.
- W2073024893 cites W2316346216 @default.
- W2073024893 cites W2316685588 @default.
- W2073024893 cites W4211087050 @default.
- W2073024893 cites W4252597945 @default.
- W2073024893 doi "https://doi.org/10.1002/(sici)1522-2683(19990101)20:1<152::aid-elps152>3.0.co;2-a" @default.
- W2073024893 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/10065972" @default.
- W2073024893 hasPublicationYear "1999" @default.
- W2073024893 type Work @default.
- W2073024893 sameAs 2073024893 @default.
- W2073024893 citedByCount "22" @default.
- W2073024893 countsByYear W20730248932016 @default.
- W2073024893 crossrefType "journal-article" @default.
- W2073024893 hasAuthorship W2073024893A5056944346 @default.
- W2073024893 hasAuthorship W2073024893A5077860652 @default.
- W2073024893 hasConcept C11268172 @default.
- W2073024893 hasConcept C118792377 @default.
- W2073024893 hasConcept C161790260 @default.
- W2073024893 hasConcept C178790620 @default.
- W2073024893 hasConcept C184651966 @default.
- W2073024893 hasConcept C185592680 @default.
- W2073024893 hasConcept C188027245 @default.
- W2073024893 hasConcept C2777626080 @default.
- W2073024893 hasConcept C2778074193 @default.
- W2073024893 hasConcept C2778913249 @default.
- W2073024893 hasConcept C43617362 @default.
- W2073024893 hasConcept C44228677 @default.
- W2073024893 hasConcept C521977710 @default.
- W2073024893 hasConcept C94412978 @default.
- W2073024893 hasConceptScore W2073024893C11268172 @default.
- W2073024893 hasConceptScore W2073024893C118792377 @default.
- W2073024893 hasConceptScore W2073024893C161790260 @default.
- W2073024893 hasConceptScore W2073024893C178790620 @default.
- W2073024893 hasConceptScore W2073024893C184651966 @default.
- W2073024893 hasConceptScore W2073024893C185592680 @default.
- W2073024893 hasConceptScore W2073024893C188027245 @default.
- W2073024893 hasConceptScore W2073024893C2777626080 @default.
- W2073024893 hasConceptScore W2073024893C2778074193 @default.
- W2073024893 hasConceptScore W2073024893C2778913249 @default.
- W2073024893 hasConceptScore W2073024893C43617362 @default.
- W2073024893 hasConceptScore W2073024893C44228677 @default.
- W2073024893 hasConceptScore W2073024893C521977710 @default.
- W2073024893 hasConceptScore W2073024893C94412978 @default.
- W2073024893 hasIssue "1" @default.
- W2073024893 hasLocation W20730248931 @default.
- W2073024893 hasLocation W20730248932 @default.
- W2073024893 hasOpenAccess W2073024893 @default.
- W2073024893 hasPrimaryLocation W20730248931 @default.
- W2073024893 hasRelatedWork W1993450165 @default.
- W2073024893 hasRelatedWork W2001638250 @default.
- W2073024893 hasRelatedWork W2063655887 @default.
- W2073024893 hasRelatedWork W2075707960 @default.
- W2073024893 hasRelatedWork W2142372529 @default.
- W2073024893 hasRelatedWork W2342858580 @default.
- W2073024893 hasRelatedWork W2789704176 @default.
- W2073024893 hasRelatedWork W2949153590 @default.
- W2073024893 hasRelatedWork W2950552742 @default.
- W2073024893 hasRelatedWork W2951494344 @default.
- W2073024893 hasVolume "20" @default.
- W2073024893 isParatext "false" @default.
- W2073024893 isRetracted "false" @default.
- W2073024893 magId "2073024893" @default.
- W2073024893 workType "article" @default.