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- W2073037260 abstract "The oxidation of 2,2,3,3-tetramethylbutane in KCl-coated vessels has been studied between 440 and 540°C, and over the pressure range 60–500 Torr. The results are consistent with a simple mechanism comprising reactions (1)-(3)(CH3)3C—C(CH3)3→ 2t-C4H9(1) t-C4H9+O2→ i-C4H8+HO2(2), HO2[graphic omitted]½ H2O +¾ O2(3) After allowance for a small (< 20 %) contribution from a chain process, accurate Arrhenius parameters A1= 6.0 × 1016 s–1, E1= 290.4 kJ mol–1 have been obtained by combination with Tsang's results. From the thermochemistry of reaction (1) and literature values for k–1, values of ΔfH°298(t-Bu)= 44.0±4.0 kJ mol–1 and S°298(t-Bu)= 304.2±4.0 J K–1 mol–1 are recommended." @default.
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- W2073037260 date "1978-01-01" @default.
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- W2073037260 title "Decomposition of 2,2,3,3-tetramethylbutane in the presence of oxygen" @default.
- W2073037260 doi "https://doi.org/10.1039/f19787400366" @default.
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