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- W2073059327 abstract "Abstract Methyl methacrylate (MMA) and organochloroaluminium dimers (Al)2 form strong complexes. An investigation by cryometry and 1H-NMR led to the conclusion that the association can be formulated thus: (Al) 2 +2MMA⇄2(Al, MMA) . The value of the equilibrium constant, in bulk at 20°, is 25 l mol−1 for AlEt2Cl and 70 l mol−1 for Al2Et3Cl3. In the case of AlEtCl2, the constant is too high to be measured, the association being practically quantitative. No ternary association of styrene with the Al-MMA complex could be detected using these methods; in any case, the formation constant of such a complex would be lower than 0.1 l mol−1." @default.
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- W2073059327 date "1985-01-01" @default.
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- W2073059327 title "Homopolymerization and copolymerization of methyl methacrylate in the presence of complexing agents—I" @default.
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- W2073059327 doi "https://doi.org/10.1016/0014-3057(85)90087-4" @default.
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