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- W2073068191 abstract "AbstractCoriolus versicolor, a wood fungus, was immobilised on Amberlite XAD-4 and used as solid-phase biosorbent for preconcentrations of rare earth elements. La(III), Th(IV), U(IV) and Ce(III) were subjected to solid-phase extraction procedure. We observed that La(III) was selectively preconcentrated, while other ions remained in solution at pH 6.0. 5.0 mL of 1.0 mol L−1 HCl was used to elaute La(III) from column. 250 mg of C. versicolor loaded on 1000 mg of XAD-4 was optimised as solid-phase matrix. Concentrations of ions in solutions were determined by inductively coupled plasma– optical emission spectrometry (ICP-OES). The calibration plot after preconcentration was linear in the range from 1.0 to 50.0 ng mL−1 for La(III). Limit of detection was found as 0.27 ng mL−1 for La(III) by SPE method. Relative standard deviation was found lower than 6.7% for 1.0 ng mL−1 of La(III) solution (n = 10). The sensitivity of ICP-OES was improved by a factor of 46.8. The applicability of the method was validated through the analysis of certified reference samples of tea (NCS ZC-73014) and spinach (NCS ZC-73013).Keywords: Lanthanumrare earth elementsselective preconcentrationCoriolus versicolorsolid-phase extraction" @default.
- W2073068191 created "2016-06-24" @default.
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- W2073068191 date "2013-09-11" @default.
- W2073068191 modified "2023-10-01" @default.
- W2073068191 title "Selective preconcentration of Lanthanum(III) by<i>Coriolus versicolor</i>immobilised on Amberlite XAD-4 and its determination by ICP-OES" @default.
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- W2073068191 doi "https://doi.org/10.1080/03067319.2013.831412" @default.
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