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- W2073076933 abstract "The imide-bridged [3]ferrocenophane, 2-pyridyl-1,1′-ferrocenedicarboximide, served as a monodentate ligand to form the corresponding heterobimetallic complex 4 with the palladium(II) complex bearing the tridentate podand ligand, through displacement of the ancillary acetonitrile. The X-ray crystal-structure determination revealed that the pyridyl nitrogen of the ferrocenophane coordinates to the palladium center with distortion of the ferrocenophane moiety, which lies below the coordination plane of palladium. Such a structure is considered to be present even in solution, resulting in four nonequivalent broad signals of Cp protons in the 1H-NMR spectrum, due to the electronic environment effect of the coordination plane of palladium. A π–π stacking interaction was observed between the benzene ring of the podand moieties and the pyridine ring of the neighboring molecule in the crystal packing of 4." @default.
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- W2073076933 date "2000-04-01" @default.
- W2073076933 modified "2023-09-26" @default.
- W2073076933 title "A novel heterobimetallic complex composed of the imide-bridged [3]ferrocenophane and the tridentate palladium(II) complex" @default.
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- W2073076933 doi "https://doi.org/10.1016/s0022-328x(99)00748-2" @default.
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