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- W2073089206 abstract "Potassium aryltrifluoroborates are cross-coupled with aryl and heteroaryl chlorides using a 4-hydroxyacetophenone oxime-derived palladacycle as precatalyst, K2CO3 as base, and TBAB as additive in refluxing water under conventional and microwave heating affording the corresponding biphenyls under phosphine-free conditions. For the arylation of allyl and benzyl chlorides, KOH is used as base in acetone-water (3:2) at rt or 50 degrees C using 0.1 mol % Pd loading providing allylbenzenes and diarylmethanes, respectively." @default.
- W2073089206 created "2016-06-24" @default.
- W2073089206 creator A5015456687 @default.
- W2073089206 creator A5042906839 @default.
- W2073089206 date "2008-10-04" @default.
- W2073089206 modified "2023-09-27" @default.
- W2073089206 title "First Cross-Coupling Reaction of Potassium Aryltrifluoroborates with Organic Chlorides in Aqueous Media Catalyzed by an Oxime-Derived Palladacycle" @default.
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- W2073089206 doi "https://doi.org/10.1021/ol802024j" @default.
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