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- W2073103682 abstract "Abstract The synthesis and spectroscopic characterization of the first silylated mixed‐chalcogen reagent, Me 3 Si–SeS–SiMe 3 , is presented. This reagent is shown to be an effective and efficient delivery source of both sulfur and selenium as demonstrated in the synthesis of a [Cu 84 Se 42– x S x (PEt 2 Ph) 24 ] ( x ≈ 15) cluster. The reaction proceeds with chalcogen‐chalcogen bond cleavage and the resulting X‐ray crystal structure of [Cu 84 Se 42– x S x (PEt 2 Ph) 24 ] illustrates the intimate mixing of sulfur and selenium within the cluster core." @default.
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- W2073103682 date "2007-10-01" @default.
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- W2073103682 title "Me3Si–SeS–SiMe3: A Reagent for the Synthesis of the Mixed Sulfo-Selenide Cluster [Cu84Se42–xSx(PEt2Ph)24]" @default.
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- W2073103682 doi "https://doi.org/10.1002/zaac.200700262" @default.
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