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- W2073109993 abstract "The equilibrium conformations of three copolymers of L-proline with β-benzyl-L-glutamate were studied in 1,2-dichloroethane, m-cresol, and dichloroacetic acid by measuring the optical rotatory dispersion and the infrared absorption spectra. In m-cresol and dichloroacetic acid, the proline residues take the trans-configuration. In m-cresol their incorporation into copolymers destroys the right-handed-α-helical conformation of glutamate residues. In 1,2-dichloroethane, the proline residues assume the cis-configuration if the sequence of proline residues is long enough. If it is short, they are in the trans-configuration. The poly-L-proline-I-helix can never coexist with the α-helix." @default.
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- W2073109993 date "1969-05-01" @default.
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- W2073109993 title "The Structure of Copolymers of L-Proline with γ-Benzyl-L-glutamate in Organic Solvents" @default.
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- W2073109993 doi "https://doi.org/10.1246/bcsj.42.1332" @default.
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