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- W2073116442 abstract "Abstract The water-soluble RuII acetylacetonato–sulfoxide complexes, cis-Ru(acac)2(DMSO)2 (1) and Ru(acac)2(meso-BESE) (2), were synthesized (BESE=1,2-bis(ethylsulfinyl)ethane=EtS(O)(CH2)2S(O)Et). Both complexes were characterized by 1H and 13C{1H} NMR, UV–Vis, and IR spectroscopies, as well as MS, elemental analysis, solution conductivity, and cyclic voltammetry, while the molecular structure of 2 was determined also by X-ray crystallography. All sulfoxide ligands are S-bonded. The complexes were tested against human breast cancer cells (MDA-MB-435S) using an in vitro MTT assay, a colorimetric determination of cell viability; IC50 values of >2000 and 1500 ± 100 μM were determined for 1 and 2, respectively, while cisplatin exhibits an IC50 value of 30 ± 5 μM." @default.
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- W2073116442 date "2003-08-01" @default.
- W2073116442 modified "2023-09-30" @default.
- W2073116442 title "Ruthenium(II) acetylacetonato–sulfoxide complexes" @default.
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- W2073116442 doi "https://doi.org/10.1016/s1387-7003(03)00164-3" @default.
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