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• W2073121533 endingPage "15754" @default.
• W2073121533 startingPage "15741" @default.
• W2073121533 abstract "The polyatomic tetrahydroxytetraindium(III) cations, In4(OH)48+, have been synthesized in 94% of the sodalite cavities of zeolite Y (FAU, Si/Al = 1.69). In−Y (|In57.8[In5]1.8|[Si121Al71O384]−FAU or In66.8−Y) was prepared by the oxidative solid state ion exchange (OSSIE) method from In0 and single crystals of Tl−Y under anhydrous conditions at 623 K. One of these was exposed to the atmosphere and then zeolitically dry oxygen, both at 623 K, to give In−Y[In4(OH)4] (|In7.6[In4(OH)4]7.5[In(OH)2]2.0|[Si121Al71O384]−FAU or In39.6(OH)34.0−Y). The structures of In−Y and In−Y[In4(OH)4] were determined by single crystal crystallography with synchrotron X-radiation. They were refined in the space group Fd3m̅ (a = 24.863(1) and 24.518(1) Å) with all unique data to the final error indices R1 = 0.050 and 0.057 for the 1110 and 1037 reflections for which Fo > 4σ(Fo), respectively. The In in In−Y is mostly In+; some In57+ clusters are present in sodalite cavities. Upon oxidation in the presence of water, 41% of the In exited the zeolite. Most of the remainder formed In4(OH)48+ clusters in the sodalite cavities of In−Y[In4(OH)4]. In4(OH)48+ is a tetrahedrally distorted In4O4 cube with a hydrogen atom bound to each oxygen atom. In In4(OH)48+, each In3+ ion lies opposite a double 6-ring and is 6-coordinate octahedral with three bonds to OH− anions (2.245(4) Å) and three to framework oxygens (2.198(5) Å); each OH− ion is near a single 6-ring to which it hydrogen bonds. Small amounts of In(OH)2+, In2+, and In+ were also found." @default.
• W2073121533 created "2016-06-24" @default.
• W2073121533 creator A5033582432 @default.
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• W2073121533 creator A5060636927 @default.
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• W2073121533 creator A5081757739 @default.
• W2073121533 date "2010-09-01" @default.
• W2073121533 modified "2023-09-25" @default.
• W2073121533 title "Tetrahydroxytetraindium(III) Nanoclusters, In₄(OH)₄⁸⁺, in Air-Oxidized Fully In-Exchanged Zeolite Y (FAU, Si/Al = 1.69). Preparation and Crystal Structures of In−Y and In−Y[In₄(OH)₄]" @default.
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• W2073121533 doi "https://doi.org/10.1021/jp1057836" @default.
• W2073121533 hasPublicationYear "2010" @default.
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