Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073134444> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2073134444 endingPage "168" @default.
- W2073134444 startingPage "158" @default.
- W2073134444 abstract "The adsorption behavior of mixtures of the enantiomers of 2,2,2-(trifluoro)-1-(9-anthryl)-ethanol (TFAE) on a quinidine carbamate bonded stationary phase was studied as an example of competitive binary adsorption on a Pirkle-type chiral adsorbent. A model of the adsorption isotherms is proposed and discussed. Binary adsorption isotherms derived by combination of the single-component isotherms of the two enantiomers in the framework of the classical bi-Langmuir model allow the correct prediction of the retention times of the elution bands of the components of binary mixtures but fail properly to predict the separation of the two enantiomers. Use of a quadratic model was needed to improve the agreement between calculated and experimental chromatograms of binary mixtures. The existence of a third type of adsorption sites besides the high-energy enantioselective and the low-energy nonselective sites was assumed. These sites have a low interaction energy, exhibit some affinity toward (S)-TFAE, but none toward (R)-TFAE." @default.
- W2073134444 created "2016-06-24" @default.
- W2073134444 creator A5022306305 @default.
- W2073134444 creator A5087309515 @default.
- W2073134444 creator A5089250649 @default.
- W2073134444 date "2007-01-01" @default.
- W2073134444 modified "2023-10-17" @default.
- W2073134444 title "Empirical development of a binary adsorption isotherm based on the single-component isotherms in the framework of a two-site model" @default.
- W2073134444 cites W1969839904 @default.
- W2073134444 cites W1975055014 @default.
- W2073134444 cites W1986930435 @default.
- W2073134444 cites W1994444932 @default.
- W2073134444 cites W1997636790 @default.
- W2073134444 cites W2002704298 @default.
- W2073134444 cites W2007353016 @default.
- W2073134444 cites W2012887210 @default.
- W2073134444 cites W2016277562 @default.
- W2073134444 cites W2023261903 @default.
- W2073134444 cites W2034006673 @default.
- W2073134444 cites W2036289614 @default.
- W2073134444 cites W2040787825 @default.
- W2073134444 cites W2043177511 @default.
- W2073134444 cites W2045703351 @default.
- W2073134444 cites W2048152638 @default.
- W2073134444 cites W2054745603 @default.
- W2073134444 cites W2076732159 @default.
- W2073134444 cites W2092464372 @default.
- W2073134444 cites W2749574849 @default.
- W2073134444 cites W46176729 @default.
- W2073134444 doi "https://doi.org/10.1016/j.chroma.2006.10.090" @default.
- W2073134444 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17126352" @default.
- W2073134444 hasPublicationYear "2007" @default.
- W2073134444 type Work @default.
- W2073134444 sameAs 2073134444 @default.
- W2073134444 citedByCount "20" @default.
- W2073134444 countsByYear W20731344442012 @default.
- W2073134444 countsByYear W20731344442013 @default.
- W2073134444 countsByYear W20731344442015 @default.
- W2073134444 countsByYear W20731344442016 @default.
- W2073134444 countsByYear W20731344442019 @default.
- W2073134444 countsByYear W20731344442020 @default.
- W2073134444 countsByYear W20731344442021 @default.
- W2073134444 crossrefType "journal-article" @default.
- W2073134444 hasAuthorship W2073134444A5022306305 @default.
- W2073134444 hasAuthorship W2073134444A5087309515 @default.
- W2073134444 hasAuthorship W2073134444A5089250649 @default.
- W2073134444 hasConcept C121332964 @default.
- W2073134444 hasConcept C12143843 @default.
- W2073134444 hasConcept C150394285 @default.
- W2073134444 hasConcept C168167062 @default.
- W2073134444 hasConcept C178790620 @default.
- W2073134444 hasConcept C185592680 @default.
- W2073134444 hasConcept C33923547 @default.
- W2073134444 hasConcept C43617362 @default.
- W2073134444 hasConcept C48372109 @default.
- W2073134444 hasConcept C486523 @default.
- W2073134444 hasConcept C73826308 @default.
- W2073134444 hasConcept C94375191 @default.
- W2073134444 hasConcept C97355855 @default.
- W2073134444 hasConceptScore W2073134444C121332964 @default.
- W2073134444 hasConceptScore W2073134444C12143843 @default.
- W2073134444 hasConceptScore W2073134444C150394285 @default.
- W2073134444 hasConceptScore W2073134444C168167062 @default.
- W2073134444 hasConceptScore W2073134444C178790620 @default.
- W2073134444 hasConceptScore W2073134444C185592680 @default.
- W2073134444 hasConceptScore W2073134444C33923547 @default.
- W2073134444 hasConceptScore W2073134444C43617362 @default.
- W2073134444 hasConceptScore W2073134444C48372109 @default.
- W2073134444 hasConceptScore W2073134444C486523 @default.
- W2073134444 hasConceptScore W2073134444C73826308 @default.
- W2073134444 hasConceptScore W2073134444C94375191 @default.
- W2073134444 hasConceptScore W2073134444C97355855 @default.
- W2073134444 hasIssue "1-2" @default.
- W2073134444 hasLocation W20731344441 @default.
- W2073134444 hasLocation W20731344442 @default.
- W2073134444 hasOpenAccess W2073134444 @default.
- W2073134444 hasPrimaryLocation W20731344441 @default.
- W2073134444 hasRelatedWork W1501144072 @default.
- W2073134444 hasRelatedWork W1911561015 @default.
- W2073134444 hasRelatedWork W1972364978 @default.
- W2073134444 hasRelatedWork W1993761582 @default.
- W2073134444 hasRelatedWork W2014194561 @default.
- W2073134444 hasRelatedWork W2030205995 @default.
- W2073134444 hasRelatedWork W2119552130 @default.
- W2073134444 hasRelatedWork W2353232367 @default.
- W2073134444 hasRelatedWork W2393944978 @default.
- W2073134444 hasRelatedWork W2577007121 @default.
- W2073134444 hasVolume "1138" @default.
- W2073134444 isParatext "false" @default.
- W2073134444 isRetracted "false" @default.
- W2073134444 magId "2073134444" @default.
- W2073134444 workType "article" @default.