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• W2073149091 abstract "We describe a simple local density functional theory for screened interactions between macroions and apply it to electric double layers. The approach incorporates the strong correlations between screening ions at high densities, and reduces to the Poisson-Boltzmann equations at low densities. Results for monovalent ions are in excellent agreement with Monte Carlo (MC) and inhomogeneous hypernetted chain (IHNC) calculations. Nonlocal effects are important for divalent ions at small macroion separations and high surface charge densities. A simple weighted density approximation qualitatively reproduces MC and IHNC results in this regime, and provides a simple explanation for the onset of attractive interactions between like-charged plates." @default.
• W2073149091 created "2016-06-24" @default.
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• W2073149091 date "1990-05-01" @default.
• W2073149091 modified "2023-10-17" @default.
• W2073149091 title "Density Functional Theory of Ionic Screening: When Do Like Charges Attract?" @default.
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• W2073149091 doi "https://doi.org/10.1209/0295-5075/12/1/015" @default.
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