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- W2073161015 abstract "An intuitive assignment of absorption bands of Ce-doped $R{text{AlO}}_{3}$ ($R=text{Gd}$, Y, and Lu) perovskites suggested by some authors is compromised. We use semiempirical approaches based on the extended Huckel method to calculate the energy-level scheme of the cluster containing Ce and its nearest O neighbors in true $R{text{AlO}}_{3}$ ($R=text{La}$, Gd, Y, and Lu) structures. Our calculations show a different origin for the energy levels involved in the absorption process than might intuitively be suggested. Some quantitative aspects also reasonably correspond to experimental observation." @default.
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- W2073161015 date "2009-05-28" @default.
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- W2073161015 title "Assignment of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mn>4</mml:mn><mml:mi>f</mml:mi><mml:mtext>−</mml:mtext><mml:mn>5</mml:mn><mml:mi>d</mml:mi></mml:mrow></mml:math>absorption bands in Ce-doped<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mi>R</mml:mi><mml:msub><mml:mrow><mml:mtext>AlO</mml:mtext></mml:mrow><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>(<mml:math xmlns:mml=http://www.w3.org/1998/…" @default.
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- W2073161015 doi "https://doi.org/10.1103/physrevb.79.195130" @default.
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