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- W2073162753 abstract "The solubility of oxygen in niobium and solid-solution alloys of niobium with other transition metals of Groups IVA, VIA, VIIA and VIIIA has been measured. The solubility of oxygen in niobium over the temperature range 700°C–1550°C obeys the relation: −logeN = 8,6oo/RT + 0.516 where N is the atomic fraction of oxygen in solution. Additions of molybdenum, rhenium and ruthenium to niobium all reduce oxygen solubility, zero solubility being reached when the electron/atom ratio of the alloy is about 5.75. Additions of titanium increase the oxygen solubility, but zirconium, which forms a very stable oxide ZrO2, reduces oxygen solubility markedly. It is concluded that the solubility of oxygen in transition metal alloys is largely electronic in nature, solubility being small if the electron/atom ratio of the alloy exceeds 5.75, and being very much larger in alloys of a lower electron/atom ratio, the oxygen dissolving with a positive charge." @default.
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- W2073162753 date "1962-02-01" @default.
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- W2073162753 title "The solubility of oxygen in transition metal alloys" @default.
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- W2073162753 doi "https://doi.org/10.1016/0022-5088(62)90060-7" @default.
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