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- W2073168055 abstract "Reaction of the novel ruthenacyclopentatriene [(η5-C5H5)Ru(C4Ph2H2)Br] (1) with isocyanides gives the imino-2,5-diphenylcyclopentadiene complexes [(η5-C5H5Ru(η4-C5Ph2H2NR)Br] (2, R = Me, Et, Cy, t-Bu, 2,6-Me2C6H3); a novel fluxional process involving phenyl substituent rotation and imino nitrogen inversion has been identified for 2 (R = t-Bu, 2,6-Me2C6H3), the interpretation of which is supported by the X-ray crystal structure determination of 2 (R = t-Bu)." @default.
- W2073168055 created "2016-06-24" @default.
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- W2073168055 date "1987-05-01" @default.
- W2073168055 modified "2023-10-16" @default.
- W2073168055 title "The chemistry of cyclopentadienyl-ruthenacyclopentatrienes: novel carbon monoxide and isocyanide insertion reactions in [η5-C5H5)Ru(η4-C5Ph2H2NBut)Br]" @default.
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- W2073168055 doi "https://doi.org/10.1016/0022-328x(87)80137-7" @default.
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