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- W2073168737 abstract "The results of ESR investigations of Tl2+-centres in NaCl, KCl, RbCl, KBr and of Pb3+-centres in KCl are reported. The g-factor and the heavy-metal hyperfine (hf) constant as well as superhyperfine (shf) constants for the six nearest neighbour halogen nuclei are determined. The quadrupole interaction is analyzed in KBr:Tl2+. An interpretation of the shf- and the hf-interaction is presented. Model calculations show that the complex formed by the centre ion and the six halogen ligands is strongly determined by covalent bonding. Es wird über Ergebnisse von ESR-Untersuchungen an Tl2+-Zentren in NaCl, KCI, RbCl, KBr und an Pb3+-Zentren in KCl berichtet. Der g-Faktor, die Hyperfeinkonstante des Schwermetallions und die Superhyperfeinkonstanten der sechs nächstbenachbarten Halogenkerne werden bestimmt. Die Quadrupolwechselwirkung wird für KBr: Tl2+ analysiert. Eine Interpretation der Hyperfein- und Superhyperfeinwechselwirkung wird gegeben. Die Modellrechnungen zeigen, daß der Komplex, der vom Zentrenion und den sechs Halogenliganden gebildet wird, wesentlich durch kovalenbe Bindung gekennzeichnet ist." @default.
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- W2073168737 date "1975-03-01" @default.
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- W2073168737 title "ESR investigations of Tl2+- and Pb3+-centres in alkali halides" @default.
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- W2073168737 doi "https://doi.org/10.1002/pssb.2220680124" @default.
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