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- W2073177797 abstract "Size exclusion chromatography and 29Si-NMR spectroscopy have been used to investigate the evolution of low-molecular weight molecules during the synthesis of poly(methylphenylsilane) by alkali metal-mediated reductive coupling in diethyl ether, tetrahydrofuran and toluene, revealing clear evidence for the important role played by a dimer. In addition, the distinct origins of the stable cyclic oligomers that are ubiquitous side products of these reactions have been established, cyclopentamers being formed through endbiting during chain growth and cyclohexamers by a degradative backbiting reaction." @default.
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- W2073177797 date "2003-11-01" @default.
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- W2073177797 title "The role of oligomers in the synthesis of polysilanes by the Wurtz reductive coupling reaction" @default.
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- W2073177797 doi "https://doi.org/10.1016/s0022-328x(03)00641-7" @default.
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