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- W2073190251 abstract "This paper reports fundamental defect energies in CsF, β-CsCl, CaBr2, CaI2, Ga2O3, Ti2O3, Rh2O3 and V2O3 obtained by simple extrapolation procedures, and in CaCl2 by direct atomistic simulation. It is suggested that CsF, β-CsCl and CaBr2 will exhibit mixed lattice disorder, and that in Ti2O3, Rh2O3 and V2O3 Schottky and anion Frenkel energies differ by less than 1 eV. The implications of mixed disorder for the interpretation of Arrhenius energies of diffusion are examined. For CsF and β-CsCl these are shown to be of the usual type, whereas the temperature dependence of the diffusion coefficients in CaBr2 is predicted to be more complicated." @default.
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- W2073190251 date "1982-09-01" @default.
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- W2073190251 title "Mixed lattice disorder in ionic materials" @default.
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- W2073190251 doi "https://doi.org/10.1016/0167-2738(82)90007-8" @default.
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