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• W2073220908 abstract "The first 1,3-dibora-2-aza-[3]ferrocenophanes (1 and 2) were obtained by cleavage of the SiN bonds of heptamethyldisilazane using 1,1′-bis(dibromoboryl)ferrocene and 1,1′-bis[bromo(methyl)boryl]ferrocene respectively. Reactions between 1,1′-bis[dialkylamino(halogeno)boryl]ferrocenes and Li2E (E = O, S, Se, or Te) led to the first 1,3-dibora-2-chalcogena-[3]ferrocenophanes (3a–3d, and 4c). The X-ray structure determination of 1,3-bis(diisopropylamino)-1,3-dibora-2-selena-[3]ferrocenophane (4c) (monoclinic; space group, P21/n) reveals a staggered conformation and a slightly titled arrangement (6.4°) of the cyclopentadienyl rings. The [3]ferrocenophanes were characterized by NMR spectroscopy in solution and in the solid state (4c: 77Se CP MAS NMR)." @default.
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• W2073220908 date "1995-04-01" @default.
• W2073220908 modified "2023-10-03" @default.
• W2073220908 title "1,3-Dibora-[3]ferrocenophanes; synthesis and characterization" @default.
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• W2073220908 doi "https://doi.org/10.1016/0022-328x(94)05320-b" @default.
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